• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    1. A laminated pane comprising only a glass sheet and a layer of transparent plastics material, characterised in that the layer of transparent plastics material has properties of absorption of energy and interior protection defined by a scratch resistance greater than 20 g measured with the Erichsen type 413 apparatus and an abrasion resistance according to European Standard R43 such that the haze difference is less than 4% and at a thickness of about 0.5 mm a flow stress sigma y at -20 degrees C not exceeding 3 daN/mm**2 , a rupture stress sigma R at +20 degrees C of at least 2 daN/mm**2 , a lengthening at rupture epsilon R at +20 degrees C from 250% to 500%, and a tear resistance Ra at +20 degrees C of at least 9 daN/mm**2 , and in that the layer of plastics material is formed essentially of a polyurethane obtained by continuous reactive casting on a flat horizontal support of a reaction mixture of an isocyanate component and a polyol component, the isocyanate component comprising at least one aliphatic or cycloaliphatic di-isocyanate or a di-isocyanate prepolymer, this component having a viscosity measured at +40 degrees C less than about 5 Pas, the isocyanate component containing urea functions, the content of urea being up to 10% of the total weight of isocyanate component, the urea content preferably being from 5 to 7%, and the polyol component comprising at least one long difunctional polyol of molecular weight from 500 to 4000 and at least one short polyol as a chain lengthening agent, the ratio of isocyanate group equivalents to hydroxyl group equivalents is about 1, and the proportions between the different polyols are selected so that the number of hydroxyl group equivalents due to the short diol represents from 20 to 70% of the total hydroxyl groups.
    公开号:SU1491326A3
    申请号:SU843791615
    申请日:1984-07-10
    公开日:1989-06-30
    发明作者:Браве Жан-Луи；Кольмон Даниель；Дод Жерар；Моншо Мишель-Жан
    申请人:Сэн-Гобэн Витраж (Фирма)；
    IPC主号:
    专利说明:

    spoon, then covered with a separating layer, followed by polymerization at 120 ° C for 25 minutes.
    After polymerization, the resulting film is peeled off the substrate. It is used to make multi-layered glasses.
    The mechanical properties of laminated glasses manufactured using the film of Example 1 are determined as follows.
    The film is placed on a layer of silicate glass with a thickness of 2.6 mm. The connection of the two layers is carried out in two stages: the compound is preliminarily pressed between the two rollers of the rolling machine, and then the obtained double-layer glass is placed in an autoclave, which is kept for 10 hours under a pressure of 10 bar and at -135 ° C.
    The resulting double-layered glass is absolutely transparent.
    The adhesion between the silicate-I o glass layer and the polyurethane film is defined as follows.
    A 5 cm wide strip is cut out of double-layer glass. One end of this strip is fixed and pulled in a direction perpendicular to the surface of the glass at a speed of 5 cm per minute. The test is carried out at 20 ° C. The average tractive effort required to strip the strip is recorded. This value is 10 daN / 5 cm.
    Impact resistance tests at various temperatures are also carried out.
    The first impact strength test is carried out with a steel ball weighing 0.260 kg (a test with a heavy ball), which falls on the central part of the sample, having a square shape with a side of 30.5 cm and installed in a rigid frame. The drop height is approximately measured, at which 90% of the samples are not penetrated through the ball.
    one
    For the double-layer glass obtained in Example 1, this height is 12 m.
    A second impact strength test is conducted with a steel ball weighing 0.227 kg and a diameter of 38 mm (light ball test) at -20 ° C and the results are 12 and 11 meters respectively.
    yh
    ten
    15
    ,
    A91326
    The scratch resistance of the double-layer glass 32-g.
    The scratch resistance is measured by a test carried out using an Eriksen type 413 instrument. The load on the diamond head is measured to obtain a scratch in a film connected to a glass substrate.
    After abrasive treatment, the film shows a transparency deviation of 0.94%.
    Abrasion resistance is measured according to European standard P42. A sample of the abrasive treatment with an abrasive wheel after 100 vol, the abrasive wheel is measured using a spectrophotometer, the transparency of the part treated with the abrasive wheel and the untreated part. The deviation of this value is judged on resistance to wear.
    Example 2. Example 1 is repeated with the difference that a mixture of polytetramethylene glycol mol.m. is used as the polyol component. 1000, 1,4-butanediol and polycaprolac-trietol with a ratio of hydroxyl equivalents of 0.35: 0.55: 0.10.
    The resulting mixture is processed into a film with a thickness of 0.66 mm
    Two-layer glass, manufactured using the film of example 2, has the following mechanical properties: 11 daN / 5 cm adhesion; 11 m durability for dough with a ball, 13.5 m and 13.5 m for dough and 40 ° С
    20
    25
    thirty
    35
    with a light bulb at -20 C, respectively; scratch resistance 35 g; abrasion transparency deviation 1 7
    I, / o.
    Example 3, Example 1 is repeated with the difference that as
    45 polyol component use a mixture of polytetramethylene glycol mol. 1000, 1,4-butanediol and polycaprolactontriol with a ratio of hydroxyl equivalents of 0.35: 0.45: 0.20.
    50 The resulting mixture is processed into a film with a thickness of 0.70 mm.
    The mechanical properties of double-layer glass made using the film obtained: coupling 11 daN / 5 cm; 8 m durability at impact with a dough ball, 11 and 11 m at dough with a light ball HHI-20 C 40 C, respectively; scratch resistance 35 g; off 5
    transparency at abrasive processing 1.2%.
    Example 4-6. Example 1 is repeated with the difference that the polyurethane film is placed on a layer of silicate glass with a thickness of 2.4 and 5 mm, respectively.
    Optical-mechanical properties of laminated glass are given in the table.
    Examples 7 and 8, Example 2 is repeated with the difference that the polyurethane film is laid on a layer of silicate glass 2 and 5 mm thick correspondingly.
    The test results of laminated glass are shown in the table.
    Example 9 (comparative). Example 1 is repeated, with the difference that polyetherdiol based on adipic and sebacic acids: caprolactone, 2,2-dimethyl-1,3-propanediol and 1,4-butanediol is used as the polyol component.
    The mechanical properties of the glass prepared using the resulting film: 8 daN / 5 cm grip test with a 8 m heavy ball, 9.5 and 9 m light ball test; scratch resistance 22 g; transparency deviation of 3%.
    Example 10 (comparative). Example 1 is repeated with the difference that 4,4-methylene bis (cyclohexyl isocyanate) containing 20% trans-trans isomer is used as the isocyanate component. 65% cis-trans isomer and 15% cis-cis isomer
    The mechanical properties of glass manufactured using the obtained film: an 8dN / 5 cm adhesion test with a 6.5 m heavy ball, a 7.5 and 8 m light ball test; scratch resistance 18 g; transparency deviation 4%,
    Example 11 (comparative). Example 2 is repeated with the difference that a mixture of 2,4-toluene diisocyanate and 2,6-toluene diisocyanate and a ratio of 65:35 is used as the isocyanate component.
    913266
    The mechanical properties of glass manufactured using the film obtained: a clutch of 7 daN / 5 cm; 8 m ball test; test with a light ball 9 and 10 m; scratch resistance 20 g; transparency deviation of 3%.
    10 Example 12 (comparative). Example 1 is repeated with the difference that ethylene glycol, N-methyldithanol g amine, trimethylol propane and polycaprolactone diol are used as the polyol component.
    The mechanical properties of the glass manufactured using the obtained film: grip 8 daN / 5 cm {test with a heavy ball of 6.0 m, test with a light ball of 9 and 10.0 m; scratch resistance 20 g; transparency deviations of 2.5%.
    25
    权利要求:
    Claims (1)
    [1]
    Invention Formula
    Laminated glass made of a layer of silicate glass and a polyurethane layer applied on it, characterized in that, in order to improve optical and mechanical properties, the polyurethane layer is made of polyurethane based on 3-isocyanatomethyl-3, 5,5-trimethylcyclohexyl isocyanate containing urea groups and isocyanate groups in the amount of 31.5%, and a mixture of polytetramethylene glycol mol.m.1000 with 1,4-butanediol with a ratio of hydroxyl equivalents of 0.37: 0.63 or a mixture of polytetramethylene glycol mol.m. . 1000 with 1,4-butanediol and polycaprolactonol at a ratio of hydroxyl equivalents of 0.35: 0.45-0.55: 0.10-0.20, respectively, at a ratio of isocyanate equivalents
    hydroxyl equivalents 1, and the glass layer is made 2-5 mm thick, and the layer on the basis of polyurethane50 is 0.660-0.755 mm thick.
    35
    40
    Editor L. Veselovska
    Compiled by G, Russian
    Tehred L. Serdyukova Proofreader A. Kozoriz
    Order 3762/58
    Circulation 415
    VNIIPI State Committee for Inventions and Discoveries at the State Committee on Science and Technology of the USSR 113035, Moscow, Zh-35, Raushsk nab. D. 4/5
    Production and publishing plant Patent, Uzhgorod, st. Gagarin, 101
    Subscription
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    同族专利:
    公开号 | 公开日
    BR8403426A|1985-06-25|
    FR2549037A1|1985-01-18|
    IE841759L|1985-01-11|
    MA20175A1|1985-04-01|
    ES8507436A1|1985-09-01|
    PT78883B|1986-06-05|
    FI77602B|1988-12-30|
    FI842766A|1985-01-12|
    PT78883A|1984-08-01|
    HU194770B|1988-03-28|
    DK163039B|1992-01-13|
    IN162382B|1988-05-21|
    PH26588A|1992-08-19|
    IL72360A|1994-01-25|
    NZ208854A|1987-11-27|
    NO161967B|1989-07-10|
    IE57796B1|1993-04-07|
    YU120684A|1986-12-31|
    JPH0567419B2|1993-09-24|
    IL72360D0|1984-11-30|
    DK337184A|1985-01-12|
    EP0131523A3|1985-02-20|
    AT31896T|1988-01-15|
    FI77602C|1989-04-10|
    HUT40364A|1986-12-28|
    ZA845292B|1986-10-29|
    NO161967C|1989-10-18|
    YU43368B|1989-06-30|
    AU575059B2|1988-07-21|
    FR2549037B1|1985-10-18|
    DK163039C|1992-06-09|
    DE3468647D1|1988-02-18|
    EP0131523B1|1988-01-13|
    AU3045684A|1985-01-17|
    EP0131523A2|1985-01-16|
    FI842766A0|1984-07-10|
    KR850001513A|1985-03-30|
    DK337184D0|1984-07-09|
    KR930000775B1|1993-02-04|
    NO842804L|1985-01-14|
    ES534172A0|1985-09-01|
    JPS6071253A|1985-04-23|
    CA1261241A|1989-09-26|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    EA008369B1|2005-04-12|2007-04-27|Светлана Сергеевна Стацевич|Method of advertising information and information device|US4024113A|1976-04-28|1977-05-17|Ppg Industries, Inc.|Polycarbonate polyurethanes based on particular aliphatic/cycloaliphatic polycarbonates|
    DE2629779C3|1976-07-02|1985-04-04|Saint Gobain|Process for the production of a two-layer film with self-healing properties using polyurethanes as a shatterproof layer on safety glass|
    FR2385751B1|1977-03-28|1980-12-26|Ppg Industries Inc|
    FR2442128B1|1978-11-23|1981-06-26|Saint Gobain|
    FR2470682B1|1979-12-06|1983-08-12|Saint Gobain|
    CA1174577A|1980-04-30|1984-09-18|Vernon G. Ammons|Polyurethane composition for safety glass interlayer|
    FR2496089B1|1980-12-11|1984-08-24|Saint Gobain Vitrage|
    JPS6261428B2|1981-06-03|1987-12-21|Asahi Glass Co Ltd|
    DE3135672A1|1981-09-09|1983-03-24|Bayer Ag, 5090 Leverkusen|Use of low-viscosity self-curing mixtures for polyurethane interlayers in laminated panes|
    FR2549036B1|1983-07-11|1985-10-18|Saint Gobain Vitrage|SAFETY SHEET GLAZING|US4592947A|1984-06-04|1986-06-03|Sierracin Corporation|Low temperature laminatable polyurethane|
    FR2576011B1|1985-01-15|1991-10-31|Saint Gobain Vitrage|PROCESS AND DEVICE FOR MANUFACTURING SAFETY GLAZING|
    FR2576012B1|1985-01-15|1991-11-22|Saint Gobain Vitrage|PROCESS AND DEVICE FOR MANUFACTURING SAFETY GLAZING|
    IT1204812B|1986-02-19|1989-03-10|Siv Soc Italiana Vetro|PROCEDURE FOR THE MANUFACTURE OF A SAFETY GLASS FOR VEHICLES AND BUILDINGS, AND PRODUCT SO OBTAINED|
    EP0285859B1|1987-03-17|1993-06-09|Asahi Glass Company Ltd.|Reaction curable composition and products comprising a cured product of the composition|
    DE4021113A1|1990-07-03|1992-01-09|Bayer Ag|Adhesives based on polyols and polyisocyanates|
    DE4124839C1|1991-07-26|1992-07-09|Vegla Vereinigte Glaswerke Gmbh, 5100 Aachen, De|
    US5846897A|1997-03-19|1998-12-08|King Industries, Inc.|Zirconium urethane catalysts|
    FR2827855B1|2001-07-25|2004-07-02|Saint Gobain|GLAZING PROVIDED WITH A STACK OF THIN FILMS REFLECTING INFRARED AND / OR SOLAR RADIATION|
    US7595759B2|2007-01-04|2009-09-29|Apple Inc.|Handheld electronic devices with isolated antennas|
    FR3013043B1|2013-11-08|2015-11-20|Saint Gobain|SUBSTRATE COATED WITH A FUNCTIONAL LAYER STACK HAVING IMPROVED MECHANICAL PROPERTIES|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    FR8311507A|FR2549037B1|1983-07-11|1983-07-11|SAFETY SHEET GLAZING|
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